The opposite curve traces the same points backwards: \(t=0\) must give \(-1\) and \(t=\pi\) must give \(1\). \(e^{i(\pi-t)}\) does. \(e^{-it}\) traces the lower semicircle, a different set of points.
A smooth curve \(\gamma\) is a function from a real interval \([a,b]\) into \(\mathbb{C}\) with continuous, nonzero derivative; a contour is a finite chain of smooth curves joined end to end.